Effect of Al₂O₃ nanoparticle dispersion on the specific heat capacity of a eutectic binary nitrate salt for solar power applications

Molten salts can be used as heat transfer fluids or thermal storage materials in a concentrated solar power plant. Improving the thermal properties can influence the utilization efficiency of solar energy. In this study, the effect of doping eutectic binary salt solvent with Al₂O₃ nanoparticles on its specific heat capacity (cp) was investigated. The effects of the mass fraction of nanoparticles on the cp of the composite nanofluid were analyzed, using both differential scanning calorimetry measurements and molecular dynamics simulations. The specific heat capacity of the nanocomposites was enhanced by increasing the nanoparticle concentration. The maximum enhancement was found to be 8.3%, at a nanoparticle concentration of 2.0%. A scanning electron microscope was used to analyze the material morphology. It was observed that special nanostructures were formed and the specific heat capacity of the nanocomposites was enhanced by increasing the quantity of nanostructures. Simulation results of cp agreed well with the experimental data, and the potential energy and interaction energy in the system were analyzed. The change in Coulombic energy contributed to most of the large change in cp, which explains the discrepancy in values between conventional nanofluids and molten salt-based nanofluids.